Notes on the use of the vacuum stability test in the study of initiation reactivity of attractive cyclic nitramines in the C4 matrix

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896279" target="_blank" >RIV/00216275:25310/13:39896279 - isvavai.cz</a>
Result on the web
<a href="http://link.springer.com/article/10.1007%2Fs10973-012-2710-y" target="_blank" >http://link.springer.com/article/10.1007%2Fs10973-012-2710-y</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10973-012-2710-y" target="_blank" >10.1007/s10973-012-2710-y</a>

Result language
angličtina
Original language name
Notes on the use of the vacuum stability test in the study of initiation reactivity of attractive cyclic nitramines in the C4 matrix
Original language description
The zero-order reaction rates (specific rate consts.) for isothermal decompn. at 120° of plastic bonded explosives (PBXs) were measured by means of the Czech vacuum stability test, STABIL. The PBXs are based on 1,3,5-trinitro-1,3,5-triazinane (RDX), ?-1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX), cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d] imidazole (BCHMX), and ?-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (?-HNIW, ?-CL-20) with 9 wt.% of the C4 type matrix, i.e., a matrix contg. 25wt.% of polyisobutylene, 59 wt.% of dioctyl sebacate and 16 wt.% of the oil HM46. The results obtained are compared with those from a recent analogous study of PBXs using an SBR (Formex P1) binder which could increase the PBXs' reactivity in comparison with C4 matrix. These results also help to dispel a widely held view about HNIW being a relatively sensitive explosive.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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