Toward the Synthesis of Indenyl Molybdenum Compound [(eta(3)-Ind)(eta(5)-Cp)Mo(CO)(2)]: Modified Compounds and Structure of a Previously Unrecognized Intermediate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896298" target="_blank" >RIV/00216275:25310/13:39896298 - isvavai.cz</a>
Result on the web
<a href="http://pubs.acs.org/doi/abs/10.1021/om400305z" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/om400305z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om400305z" target="_blank" >10.1021/om400305z</a>
Alternative languages
Result language
angličtina
Original language name
Toward the Synthesis of Indenyl Molybdenum Compound [(eta(3)-Ind)(eta(5)-Cp)Mo(CO)(2)]: Modified Compounds and Structure of a Previously Unrecognized Intermediate
Original language description
The mechanism of synthesis of [(eta(3)-Ind')(eta(5)-Cp)Mo(CO)(2)] was studied on methyl-substituted derivatives (Ind' = 2-MeC9H6; 4,7-Me2C9H5). It was observed that the initial step involving reaction with HCl gives dimeric chloride species [{(eta(5)-Ind')Mo(CO)(2)(mu-Cl)}(2)]. This outcome differs from the structure suggested in the literature. Furthermore, it was demonstrated by various examples that compounds of the formula [{(eta(5)-Ind')Mo(CO)(2)(mu-Cl)}(2)] are convenient starting materials giving[(eta(3)-Ind')(eta(5)-Cp')Mo(CO)(2)] through the reaction with appropriate cyclopentadienides. The variability of this method was demonstrated on several examples including weakly donating Cp ligands bearing strong electron-withdrawing functional groups[C5H4COOMe, (1,2-MeOCO)(2)C5H3, and 1,2-((BuNHCO)-Bu-t)(2)C5H3] as well as Cp ligands bearing a pendant amine arm (C5H4CH2CH2NMe2). Similar eta(3)-indenyl complexes are formed when using other univalent six-electron ligands such as carba
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
32
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
3502-3511
UT code for WoS article
000321074500009
EID of the result in the Scopus database
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