The effect of molecular structure on thermal stability, decomposition kinetics and reaction models of nitric esters
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896350" target="_blank" >RIV/00216275:25310/13:39896350 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0040603113002931" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0040603113002931</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tca.2013.05.032" target="_blank" >10.1016/j.tca.2013.05.032</a>
Alternative languages
Result language
angličtina
Original language name
The effect of molecular structure on thermal stability, decomposition kinetics and reaction models of nitric esters
Original language description
The thermal stability and decompn. mechanism functions of 10 nitric esters including nitroglycerin (NG), pentaerythritol tetranitrate (PETN), trimethylolethane trinitrate (TMETN), dipentaerythritol hexanitrate (DiPEHN), trimethylolpropane trinitrate (TMPTN), erythritol tetranitrate (ETN), xylitol pentanitrate (XPN), sorbitol hexanitrate (SHN), mannitol hexanitrate (MHN), and nitroisobutylglycerol trinitrate (NIBGT) are detd. by non-isothermal TG and DSC techniques. It was found that the mean activationenergies for most nitric esters are comparable at const. heating rate (around 145 kJ mol-1), indicating that their main decompn. pathways might be the same. Based on the crit. temp. of thermal decompn., the order of mol. stability for involved nitric esters is found to be MHN { XPN { TMPTN { SHN { NIBGT { ETN { PETN { DiPEHN. The introduction of function groups to the tertiary carbon is in favor of increasing thermal stability due to increase of symmetry and rigidity of the mol.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/VG20102014032" target="_blank" >VG20102014032: Research of improvised explosives detection by dogs</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Thermochimica Acta
ISSN
0040-6031
e-ISSN
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Volume of the periodical
566
Issue of the periodical within the volume
N
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
12
Pages from-to
137-148
UT code for WoS article
000322685700020
EID of the result in the Scopus database
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