O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896431" target="_blank" >RIV/00216275:25310/13:39896431 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0022328X13001848" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0022328X13001848</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.02.033" target="_blank" >10.1016/j.jorganchem.2013.02.033</a>

Result language
angličtina
Original language name
O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand
Original language description
Thirteen organotin(IV) and low valent complexes of group 14 (Ge, Sn, Pb) containing L-NO ligand(s) (where L-NO is 2-(N, N-dimethylaminomethyl) phenolate) were synthesized and its structure described by NMR techniques in solution and X-ray techniques in the solid state (for L2(NO)SnPh(2), (L2SnCl2)-Sn-NO, (L2Ge)-Ge-NO and (LSnCl)-Sn-NO which forms a dimer). Structures and properties of prepared species have been compared with previously published germanium and tin compounds containing -OCH2CH2NMe2 as O,N- or L-CN (where L-CN is 2-(N, N-dimethylaminomethyl) phenyl) as C, N-chelating ligands. The solid state structures containing L-NO ligand(s) reveal much stronger intramolecular N -} Sn coordination than complexes containing latter two ligands.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)