N-Triazinyl Derivatives of 1-and 9-aminoanthracene: Synthesis and Photo-Physical Properties
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896466" target="_blank" >RIV/00216275:25310/13:39896466 - isvavai.cz</a>
Alternative codes found
RIV/68407700:21340/13:00218818
Result on the web
<a href="http://link.springer.com/article/10.1007%2Fs10895-013-1156-3" target="_blank" >http://link.springer.com/article/10.1007%2Fs10895-013-1156-3</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10895-013-1156-3" target="_blank" >10.1007/s10895-013-1156-3</a>
Alternative languages
Result language
angličtina
Original language name
N-Triazinyl Derivatives of 1-and 9-aminoanthracene: Synthesis and Photo-Physical Properties
Original language description
New N-triazinyl derivatives were synthesized by reaction of cyanuric chloride with 1- and 9-aminoanthracenes and subsequent nucleophilic substitution of chlorine atoms on triazinyl ring with methoxy and/or phenylamino groups. The compounds were characterized by H-1 and C-13 NMR and mass spectra. The influence of the chemical structure and solvent polarity on the UV/Vis absorption and fluorescence spectra and fluorescence quantum yields were investigated. Semi-empirical computations revealed highly polarCT states in singlet excited state manifold connected with charge-transfer from the hydrocarbon moiety to the triazinyl ring. The relationships between the CT-to-emitting state energy gap, solvent polarity and fluorescence quantum yield were discussed.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GAP208%2F10%2F0941" target="_blank" >GAP208/10/0941: Engineering of surface-modified optical processes in molecules and semiconductor quantum dots by plasmon resonances in metal nanoparticle assemblies.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Fluorescence
ISSN
1053-0509
e-ISSN
—
Volume of the periodical
23
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
13
Pages from-to
425-437
UT code for WoS article
000319079400010
EID of the result in the Scopus database
—