Oxidative addition of organic disulfides to low valent N,C,N-chelated organobismuth(I) compound: Isolation, structure and coordination capability of substituted bismuth(III) bis(arylsulfides)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896779" target="_blank" >RIV/00216275:25310/13:39896779 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.05.005" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2013.05.005</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.05.005" target="_blank" >10.1016/j.jorganchem.2013.05.005</a>

Result language
angličtina
Original language name
Oxidative addition of organic disulfides to low valent N,C,N-chelated organobismuth(I) compound: Isolation, structure and coordination capability of substituted bismuth(III) bis(arylsulfides)
Original language description
The reaction between in situ prepared THF solution of N,C,N-chelated organobismuth(I) [LBi](n) compound (not isolated), via reaction of LBiCl2 (1) (where L [o,o-C6H3(CH2NMe2)(2)]) with K[B(s-Bu)(3)H] (K-Selectride), and a set of diorganodisulfides ArSSArgave organobismuth(III) compounds LBi(SAr)(2) 2-7 (where Ar = 2-pyridyl (2), 4-metylthiazol-2-yl (3), thiofen-2-yl (4), 4-tert-butyl-1-iso-propyl-1H-imidazol-2-yl (5), 1-phenyl-1H-tetrazol-5-yl (6), 2-aminophenyl (7)). Compounds 2-7 were characterized by the help of elemental analysis, H-1 and C-13 NMR spectroscopy and in the case of 2, 3 and 6 by the help of single-crystal X-ray diffraction analysis. Compound 7 was unstable in solution and decomposed to compound LBi[S(NH)C6H4] (8), containing five-membered BiSNC2 ring, and the 2-aminothiophenol. Attempts to selectively cleave the Bi-N bond involved in this ring by an acid (such as HCl or acetic acid) failed and led only to the isolation of 1 or acetate LBi(Ac)(2) and elimination of 2-
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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