Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896784" target="_blank" >RIV/00216275:25310/13:39896784 - isvavai.cz</a>
Alternative codes found
RIV/61388971:_____/13:00392677
Result on the web
<a href="http://dx.doi.org/10.1021/om3010383" target="_blank" >http://dx.doi.org/10.1021/om3010383</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om3010383" target="_blank" >10.1021/om3010383</a>

Result language
angličtina
Original language name
Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds
Original language description
The reactions of the organoantimony(I) compound (L4Sb4)-Sb-1 (1) (where L-1 = [o-C6H4(CH=NC6H3(i-Pr)(2)-2,6)]) with diphenyldichalcogenides PhEEPh (E = S, Se, or Te) gave compounds (LSb)-Sb-1(EPh)(2) (E = S (2), Se (3), Te (4)) as the result of the oxidative addition of the antimony(I) atom across the chalcogen-chalcogen bond. The reaction of diphenyldichalcogenides PhEEPh with an in situ prepared organobismuth(I) compound (via reaction of the parent chloride (LBiCl2)-Bi-1 (5) with two equivalents of K[B(s-Bu)(3)H]) gave surprisingly diorganobismuth compounds (L2Bi)-Bi-1(EPh) (E = S (6), Se (7), Te (8)) as the major products along with only a trace amount of the intended compounds (LBi)-Bi-1(EPh)(2) (E = S (9), Se (10), Te (11)). It turned out that this is the result of instability of 9-11 in solution, and their decomposition provided compounds 6-8. The bismuth compounds containing the pincer-type ligand L-2 (L-2 = [o,o-C6H3(CH2NMe2)(2)]) containing an extra donor pendant arm were stud
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F10%2F0130" target="_blank" >GAP207/10/0130: N,C,N Chelated Chalcogenides of Heavier Group 14 and 15 Elements</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)