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Polystyrene copolymer-supported by substituted (1R,2R)-1,2-diphenylethane-1,2-diamine-copper(II) complexes: recyclable catalyst for the asymmetric Henry reaction

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39897793" target="_blank" >RIV/00216275:25310/14:39897793 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.tetasy.2014.04.004" target="_blank" >http://dx.doi.org/10.1016/j.tetasy.2014.04.004</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.tetasy.2014.04.004" target="_blank" >10.1016/j.tetasy.2014.04.004</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Polystyrene copolymer-supported by substituted (1R,2R)-1,2-diphenylethane-1,2-diamine-copper(II) complexes: recyclable catalyst for the asymmetric Henry reaction

  • Original language description

    Herein described the preparation of swelling pearl-like copolymer styrene-4-vinylbenzyl chloride crosslinked by means of tetra(ethylene glycol)-bis(4-vinylbenzyl)ether (200-800 mým). The pearl-like polymer was used to anchor (1R,2R)-1-amino-2-(2,3-dihydro-1H-isoindole-2-yl)-1,2-diphenylethane by a covalent bond; the product was subsequently transformed into the corresponding complex with Cu(II) acetate. The synthesized catalyst was used for the catalysis of the Henry reaction of functionalized aldehydeswith nitromethane in ethanol. The reactions proceeded in a polymeric matrix of the swelling catalyst at a rate comparable with the rates of reactions in a homogeneous medium. The corresponding functionalized 2-nitroethanols were formed in quantitative yields (20 °C, 24 h) with enantiomeric excess values of up to 96%. The catalyst was recycled five times without losing its effectiveness with regard to the yield and enantioselectivity; only a partial mechanical degradation of the polymeri

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA14-00925S" target="_blank" >GA14-00925S: Immobilized Enantioselective Catalysts</a><br>

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Tetrahedron Asymmetry

  • ISSN

    0957-4166

  • e-ISSN

  • Volume of the periodical

    25

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

    775-780

  • UT code for WoS article

    000336879400010

  • EID of the result in the Scopus database