Cr1/3Zr2P3O12 with Unusual Tetrahedral Coordination of Cr(III): Peculiarities of the Formation, Thermal Stability and Application as a Pigment

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39897858" target="_blank" >RIV/00216275:25310/14:39897858 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/14:00438006
Result on the web
<a href="http://dx.doi.org/10.1039/C4DT02001D" target="_blank" >http://dx.doi.org/10.1039/C4DT02001D</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C4DT02001D" target="_blank" >10.1039/C4DT02001D</a>

Result language
angličtina
Original language name
Cr1/3Zr2P3O12 with Unusual Tetrahedral Coordination of Cr(III): Peculiarities of the Formation, Thermal Stability and Application as a Pigment
Original language description
All the known chromium(III) NASICON-related phosphates are considered to be solid solutions. In these compounds chromium atoms share their position in the basic framework of the crystal lattice with other structure forming elements such as zirconium. Inour study, we have hypothesised a completely new way of structural organisation of the chromium(III) zirconium(IV) NASICON framework, consisting in the distribution of chromium over the charge-compensating atom sites with tetrahedral oxygen coordination.The possibility of formation of the corresponding phosphate, Cr1/3Zr2P3O12, was studied using a classical ceramic route and a sol-gel method. Structural affiliation of the obtained pure phase product was studied using XRD analysis. The results confirmedthat the Cr1/3Zr2P3O12 phosphate belongs to monoclinic SW-subtype of the NASICON family. In this structure, chromium atoms occupy charge-compensating sites with a strongly distorted tetrahedral oxygen environment. To the best of our know
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/EE2.3.30.0021" target="_blank" >EE2.3.30.0021: Strenthening of Research and Development Teams at the University of Pardubice</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)