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Amorphous-to-crystalline transition in Te-doped Ge2Sb2Se5 glass

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898139" target="_blank" >RIV/00216275:25310/14:39898139 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s10973-014-3910-4" target="_blank" >http://dx.doi.org/10.1007/s10973-014-3910-4</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10973-014-3910-4" target="_blank" >10.1007/s10973-014-3910-4</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Amorphous-to-crystalline transition in Te-doped Ge2Sb2Se5 glass

  • Original language description

    Differential scanning calorimetry (DSC) was used to study crystallization in Ge2Sb2Se4.5Te0.5 glass under non-isothermal conditions. The crystallization kinetics was described in terms of the autocatalytic estak-Berggren model. An extensive discussion ofall aspects of a full-scale kinetic study for a crystallization process was undertaken. In particular, the effect of Te a dagger" Se substitution on the complexity of the crystallization process was analyzed. The addition of tellurium enhances bulk crystallization originating from volume nuclei at the expense of the surface/defects-based crystallization mechanism. Significantly higher activation energy in the case of the Te-doped material was attributed to the larger mass of the combined Se-Te chains and the larger spatial restrictions for their movement. On the other hand, the slightly lower crystallization temperature of the Te-doped glass corresponds to its higher tendency for crystallization. A supplemental X-ray diffraction study

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP106%2F11%2F1152" target="_blank" >GAP106/11/1152: Reversible crystallization and structural relaxation in amorphous materials used for phase change recording</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Thermal Analysis and Calorimetry

  • ISSN

    1388-6150

  • e-ISSN

  • Volume of the periodical

    117

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    1073-1083

  • UT code for WoS article

    000340683300009

  • EID of the result in the Scopus database