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Non-isothermal crystallization kinetics of As2Se3 glass studied by DSC

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898150" target="_blank" >RIV/00216275:25310/14:39898150 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.tca.2014.01.008" target="_blank" >http://dx.doi.org/10.1016/j.tca.2014.01.008</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.tca.2014.01.008" target="_blank" >10.1016/j.tca.2014.01.008</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Non-isothermal crystallization kinetics of As2Se3 glass studied by DSC

  • Original language description

    Differential scanning calorimetry was used to study crystallization behavior in As2Se3 glass under non-isothermal conditions. The effects of changing particle size and glass-forming conditions were investigated. Based on the results of complete kinetic analysis, the crystallization kinetics was described in terms of the Johnson-Mehl-Avrami (JMA) nucleation-growth model: values of apparent activation energy and the JMA kinetic exponent were determined for all studied samples. A new conception involving the influences of the number of mechanically induced defects and amount of strains and stresses arising from the melt-quench on crystallization kinetics was introduced. The fundamental idea utilized within this conception incorporates the crucial role ofboth these considered factors, where the increased number of mechanical defects and heterogeneities effectively increases the number of primary nucleation centers, while the stress-induced defects originating from the glass-forming proced

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP106%2F11%2F1152" target="_blank" >GAP106/11/1152: Reversible crystallization and structural relaxation in amorphous materials used for phase change recording</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Thermochimica Acta

  • ISSN

    0040-6031

  • e-ISSN

  • Volume of the periodical

    579

  • Issue of the periodical within the volume

    March

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    56-63

  • UT code for WoS article

    000334894700010

  • EID of the result in the Scopus database