Synthesis and characterization of push-pull molecules bearing tetrafluorobenzene central acceptor modified with two peripheral hexyloxy and dihexylamino donors
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898166" target="_blank" >RIV/00216275:25310/14:39898166 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Synthesis and characterization of push-pull molecules bearing tetrafluorobenzene central acceptor modified with two peripheral hexyloxy and dihexylamino donors
Original language description
Starting from 1,4-diiodotetrafluorobenzene or 1,4-bis(5-bromothiophene-2-yl)tetrafluorobenzene, four new push-pull molecules were synthesized via twofold cross-coupling reactions. Suzuki-Miyaura and Sonogashira reactions were employed to gain access to target molecules. The central tetrafluorobenzene acceptor unit was modified by two peripheral N,N-dihexylamino and O-hexyloxy groups with different donating ability to generate quadrupolar D-pí-A-pí-D system with tailored intramolecular charge-transfer. The length, planarity and composition of the pí-linker between the acceptor and donors was modified by combination of 1,4-phenylene, 2,5-thienylene and acetylenic subunits in order to finely tune the linear as well as nonlinear optical properties.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/EE2.3.30.0021" target="_blank" >EE2.3.30.0021: Strenthening of Research and Development Teams at the University of Pardubice</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology
ISSN
1211-5541
e-ISSN
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Volume of the periodical
20
Issue of the periodical within the volume
září 2014
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
13
Pages from-to
249-261
UT code for WoS article
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EID of the result in the Scopus database
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