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Synthesis and characterization of push-pull molecules bearing tetrafluorobenzene central acceptor modified with two peripheral hexyloxy and dihexylamino donors

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898166" target="_blank" >RIV/00216275:25310/14:39898166 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and characterization of push-pull molecules bearing tetrafluorobenzene central acceptor modified with two peripheral hexyloxy and dihexylamino donors

  • Original language description

    Starting from 1,4-diiodotetrafluorobenzene or 1,4-bis(5-bromothiophene-2-yl)tetrafluorobenzene, four new push-pull molecules were synthesized via twofold cross-coupling reactions. Suzuki-Miyaura and Sonogashira reactions were employed to gain access to target molecules. The central tetrafluorobenzene acceptor unit was modified by two peripheral N,N-dihexylamino and O-hexyloxy groups with different donating ability to generate quadrupolar D-pí-A-pí-D system with tailored intramolecular charge-transfer. The length, planarity and composition of the pí-linker between the acceptor and donors was modified by combination of 1,4-phenylene, 2,5-thienylene and acetylenic subunits in order to finely tune the linear as well as nonlinear optical properties.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/EE2.3.30.0021" target="_blank" >EE2.3.30.0021: Strenthening of Research and Development Teams at the University of Pardubice</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology

  • ISSN

    1211-5541

  • e-ISSN

  • Volume of the periodical

    20

  • Issue of the periodical within the volume

    září 2014

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    13

  • Pages from-to

    249-261

  • UT code for WoS article

  • EID of the result in the Scopus database