Recent advances in the study of the initiation of energetic materials using characteristics of their thermal decomposition. Part I. Cyclic nitramines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898377" target="_blank" >RIV/00216275:25310/14:39898377 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/14:00434655
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Recent advances in the study of the initiation of energetic materials using characteristics of their thermal decomposition. Part I. Cyclic nitramines
Original language description
Arrhenius parameters, Ea and log A, of 17 cyclic nitramines,derived from the Russian vacuum manometric method and compatible thermoanalytical methods, have been used in this study. The detonation velocity,D, at maximum theoretical crystal density, of thenitramines in this study was taken as a characteristic of their detonation. On the basis of known relationships between their Ea and D2 values, the specific influence of some physicochemical properties on their thermal decomposition was shown. A new logarithmic relationship was found between the rate constant, of the unimolecular thermal decomposition of the nitramines studied at 230 °C, and their D values. A fundamental characteristic of this new relationship rests on the equivalency of the primary fission processes in the low-temperature thermal decomposition and on the detonation initiation of the nitramines under study. Both these relationships confirm the problems encountered in the kinetic specification of the thermal decompositi
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Central European Journal of Energetic Materials
ISSN
1733-7178
e-ISSN
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Volume of the periodical
11
Issue of the periodical within the volume
2
Country of publishing house
PL - POLAND
Number of pages
17
Pages from-to
173-189
UT code for WoS article
000340082600001
EID of the result in the Scopus database
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