Reduction of 3-Aminoquinoline-2,4(1H,3H)-diones and Deamination of the Reaction Products

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898413" target="_blank" >RIV/00216275:25310/14:39898413 - isvavai.cz</a>
Alternative codes found
RIV/62690094:18470/14:50002373 RIV/70883521:28110/14:43871791
Result on the web
<a href="http://dx.doi.org/10.1002/hlca.201300319" target="_blank" >http://dx.doi.org/10.1002/hlca.201300319</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/hlca.201300319" target="_blank" >10.1002/hlca.201300319</a>

Result language
angličtina
Original language name
Reduction of 3-Aminoquinoline-2,4(1H,3H)-diones and Deamination of the Reaction Products
Original language description
3-Aminoquinoline-2,4-diones were stereoselectively reduced with NaBH4 to give cis-3-amino-3,4-dihydro-4-hydroxyquinolin-2(1H)-ones. Using triphosgene (=bis(trichloromethyl) carbonate), these compounds were converted to 3,3a-dihydrooxazolo[4,5-c]quinoline-2,4(5H,9bH)-diones. The deamination of the reduction products using HNO2 afforded mixtures of several compounds, from which 3-alkyl/aryl-2,3-dihydro-1H-indol-2-ones and their 3-hydroxy and 3-nitro derivatives were isolated as the products of the molecular rearrangement.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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