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Tetrylenes chelated by bifunctional beta-diketiminate ligand: structure and possible applications

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898433" target="_blank" >RIV/00216275:25310/14:39898433 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/aoc.3141" target="_blank" >http://dx.doi.org/10.1002/aoc.3141</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/aoc.3141" target="_blank" >10.1002/aoc.3141</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Tetrylenes chelated by bifunctional beta-diketiminate ligand: structure and possible applications

  • Original language description

    The synthesis and structure of heteroleptic tetrylenes containing bifunctional -diketiminate ligand are reported. Compounds were prepared via a protolytic reaction of free -diketimine {N-[(2-MeO)C6H5]}NC(Me)CHC(Me)N(H){N-[(2-MeO)C6H5]} ((LH)-H-CO) and {N-[(2-MeO)C6H5]}NCHCHCHN(H){N-[(2-MeO)C6H5]} ((LH)-H-HO), respectively, with corresponding bis(amide) - M[N(SiMe3)(2)](2) (M=Ge, Sn, Pb) - in equimolar ratio or via the salt elimination route from lithium precursors generated from (LH)-H-HO/(LH)-H-CO species and slight excess of SnCl2 or GeCl2.dioxane complex. Only heteroleptic complexes were obtained by the mentioned methods. Products were characterized by multinuclear NMR spectroscopy techniques and structures of four of them have been determined by X-ray diffraction methods. Complexes (LGeCl)-Ge-HO and (LSnN)-Sn-CO(SiMe3)(2) crystallize as monomers with the three-coordinated metal centres by one chloro or amido ligand and one bidentate -diketiminato unit, in contrast to the structure

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP106%2F10%2F0924" target="_blank" >GAP106/10/0924: The electron deficient transition metal complexes containing bifunctional beta-diketiminate and cyclopentadienyl ligands ? design of new catalysts.</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Applied Organometallic Chemistry

  • ISSN

    0268-2605

  • e-ISSN

  • Volume of the periodical

    28

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    405-412

  • UT code for WoS article

    000336440900005

  • EID of the result in the Scopus database