New thiocyanato iron(II) complex with 3,5-bis(3-pyridyl)-1,2,4-thiadiazole: Synthesis, structure, magnetic and spectral properties

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898444" target="_blank" >RIV/00216275:25310/14:39898444 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.ica.2014.01.032" target="_blank" >http://dx.doi.org/10.1016/j.ica.2014.01.032</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ica.2014.01.032" target="_blank" >10.1016/j.ica.2014.01.032</a>

Result language

angličtina

Original language name

New thiocyanato iron(II) complex with 3,5-bis(3-pyridyl)-1,2,4-thiadiazole: Synthesis, structure, magnetic and spectral properties

Original language description

The new iron(II) complex [Fe(NCS)(2)(CH3OH)(2)(bpta)(2)] (bpta = 3,5-bis(3-pyridyl)-1,2,4-thiadiazole) has been prepared by refluxing Fe(NCS)(3) or Fe(NCS)(2) with thionicotinamide in methanol solution. It is supposed that the bpta ligand is generated insitu by the oxidative dimerization of thionicotinamide. The complex was characterized by X-ray structural analysis at 150 and 293 K, elemental analysis, spectral and magnetic measurements. The compound crystallizes in the monoclinic P2(1) space group, with unit cell parameters at 293 K: a = 7.869(2), b = 17.056(3), c = 12.637(3) angstrom, beta = 102.88(1)degrees. The crystal structure analysis showed that the iron atom has a distorted octahedral environment with FeN4O2 chromophore. Iron atom is coordinated by two nitrogen atoms from NCS ions, by two oxygen atoms from methanol molecules in the equatorial plane and by two nitrogen atoms of pyridine rings from dpta ligands in axial positions. The crystal lattice forms 2D supramolecular ne

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

414

Issue of the periodical within the volume

April

Country of publishing house

CH - SWITZERLAND

Number of pages

6

Pages from-to

33-38

UT code for WoS article

000334311700006

EID of the result in the Scopus database

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