Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898816" target="_blank" >RIV/00216275:25310/14:39898816 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c4dt00812j" target="_blank" >http://dx.doi.org/10.1039/c4dt00812j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4dt00812j" target="_blank" >10.1039/c4dt00812j</a>

Result language
angličtina
Original language name
Reduction of C,N-chelated chloroborane: straightforward formation of the unprecedented 1H-2,1-benzazaborolyl potassium salt
Original language description
Reduction of C,N-chelated chloroborane [2-(CH-NtBu)C6H4]BPhCl (1) with the potassium metal afforded (3,3')-bis(1-Ph-2-tBu-1H-2,1-benzazaborole) (2). Compound 2 is formed via C-C reductive coupling reaction. Subsequent reduction of 2 with two equivalentsof the potassium metal produced orange crystals of 1Ph-2tBu-1H-2,1-benzazaborolyl (Bab) potassium salt K(THF)(Bab) (3). Compound 3 is able to react with simple electrophiles (MeI or Me3SiCl) resulting in the formation of substituted 1H-2,1-benzazaboroles.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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