Opening of boroxines by N,C,N-chelated antimony(III), bismuth(III) and tin(IV) compounds

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898818" target="_blank" >RIV/00216275:25310/14:39898818 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2014.07.028" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2014.07.028</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2014.07.028" target="_blank" >10.1016/j.inoche.2014.07.028</a>

Result language
angličtina
Original language name
Opening of boroxines by N,C,N-chelated antimony(III), bismuth(III) and tin(IV) compounds
Original language description
N,C,N-intramolecularly coordinated antimony(III) and bismuth(III) oxides (LMO)(2) [where M=Sb (1), Bi (2)] and tin(IV) carbonate LSnPh(CO3) (3) [L is an abbreviation for (2,6-Me2NCH2)(2)C6H3] were shown to open six-membered boroxine rings R3B3O3 (R=Me orOMe) giving heteroboroxine compounds LM[OB(R)](2)O [where M=Sb and R=Me (4) or OMe (5); M=Bi and R=Me (6)] and LSn(Ph)[OB(R)](2)O [where R=Me (7) or OMe (8)]. Studied compounds were characterized by the help of multinuclear NMR spectroscopy and in the case of 4 and 7 by means of single-crystal X-ray diffraction analysis.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA13-00289S" target="_blank" >GA13-00289S: Heteroboroxines-A New Class of Boroxine Based Compounds</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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