T-Shaped (Donor-pi-)(2)Acceptor-pi-Donor Push-Pull Systems Based on Indan-1,3-dione
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39899798" target="_blank" >RIV/00216275:25310/15:39899798 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejoc.201500525" target="_blank" >http://dx.doi.org/10.1002/ejoc.201500525</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejoc.201500525" target="_blank" >10.1002/ejoc.201500525</a>
Alternative languages
Result language
angličtina
Original language name
T-Shaped (Donor-pi-)(2)Acceptor-pi-Donor Push-Pull Systems Based on Indan-1,3-dione
Original language description
Sixteen model (donor-pi-)(2)acceptor-pi-donor [(D-pi-)(2)A-pi-D] molecules with an extraordinary T-shaped arrangement were designed and synthesized. Indan-1,3-dione was employed as a central acceptor with electron donors linked at the C-2, C-4, and C-7 positions. These push-pull molecules represent a first systematic modification of an indan-1,3-dione-fused benzene ring. The structures and properties of all target molecules were investigated by X-ray analysis, electrochemistry, UV/Vis absorption spectroscopy, differential scanning calorimetry, electric-field-induced second-harmonic generation (EFISHG) studies, and DFT calculations. A thorough evaluation of all of the gathered data has been performed, and structure-property relationships were evaluated.Electron donors attached at the C-2 position through systems of various lengths affect the studied properties most significantly. The side donors at C-4 and C-7 can be described as auxiliary and do not dominate the observed properties. H
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA13-01061S" target="_blank" >GA13-01061S: Organic Push-Pull Molecules: Versatile Materials for Optoelectronics</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Organic Chemistry
ISSN
1434-193X
e-ISSN
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Volume of the periodical
2015
Issue of the periodical within the volume
24
Country of publishing house
DE - GERMANY
Number of pages
11
Pages from-to
5339-5349
UT code for WoS article
000359703900007
EID of the result in the Scopus database
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