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Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900112" target="_blank" >RIV/00216275:25310/15:39900112 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11243-015-9982-6" target="_blank" >http://dx.doi.org/10.1007/s11243-015-9982-6</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11243-015-9982-6" target="_blank" >10.1007/s11243-015-9982-6</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate

  • Original language description

    The synthesis, crystal structures and spectroscopy of [{Cu(mu(2)-adip)(benzim)(2)(H2O)}(n)] (1), [{Cu(mu(2)-adip)(4-pyme)(2)(H2O)}(n)] (2), [{Cu(mu(3)-adip)(nia)(2)}(n)center dot nH(2)O] (3), [{Cu(mu(2)-adip)(pydca)(2)}(n)] (4) and [{Cu(mu(4)-adip)(mna)}(n)center dot nH(2)O] (5) (adip = adipate(2-) anion, benzim = benzimidazole, 4-pyme = 4-pyridylmethanol, nia = nicotinamide, pydca = 3,4-pyridinedicarboxamide, mna = N-methylnicotinamide) are reported. The complexes under study were characterized by electronic, IR and EPR spectroscopy, and single-crystal X-ray structure analysis. The complexes form one-dimensional or two-dimensional brick-wall like coordination polymers. The coordination environments around the copper atoms of complexes 1-3 and 5 are distorted tetragonal pyramidal. The copper atom in complex 4 has tetragonal-bipyramidal coordination. Four different coordination modes of adipate ligands in the studied copper(II) complexes were observed. The coordination polymers of the c

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Transition Metal Chemistry

  • ISSN

    0340-4285

  • e-ISSN

  • Volume of the periodical

    40

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    12

  • Pages from-to

    857-868

  • UT code for WoS article

    000362899400010

  • EID of the result in the Scopus database