Structure and magnetism of novel dinuclear cobalt(II) complexes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900116" target="_blank" >RIV/00216275:25310/15:39900116 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.inoche.2015.03.038" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2015.03.038</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.inoche.2015.03.038" target="_blank" >10.1016/j.inoche.2015.03.038</a>

Result language

angličtina

Original language name

Structure and magnetism of novel dinuclear cobalt(II) complexes

Original language description

Two dinuclear cobalt(II) complexes of the formula [CO2X4(isonia)(4)] have been synthesized and structurally characterized; isonia is unidentate neutral iso-nicotinamide and X are furan-3- or furan-2-carboxylate ligands. The chromophore [CoO4N2} is formedof two iso-nicotinamide ligands and three furancarboxylate ligands where two of them bear a bridging function and one is a terminal-bidentate ligand. The magnetic data confirm a weak exchange interaction (J / hc = -2 cm(-1)) and a high single-ion zero-field splitting (D / hc = 63 and 33 cm(-1), respectively).

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry Communications

ISSN

1387-7003

e-ISSN

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Volume of the periodical

56

Issue of the periodical within the volume

June

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

3

Pages from-to

62-64

UT code for WoS article

000355045400013

EID of the result in the Scopus database

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