Thermal behavior of 1,3,5-trinitroso-1,3,5-triazinane and its melt-castable mixtures with cyclic nitramines

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900187" target="_blank" >RIV/00216275:25310/15:39900187 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tca.2015.07.010" target="_blank" >http://dx.doi.org/10.1016/j.tca.2015.07.010</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tca.2015.07.010" target="_blank" >10.1016/j.tca.2015.07.010</a>

Result language
angličtina
Original language name
Thermal behavior of 1,3,5-trinitroso-1,3,5-triazinane and its melt-castable mixtures with cyclic nitramines
Original language description
1,3,5-Trinitroso-1,3,5-triazinane, cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole (BCHMX) and epsilon-2,4,6,8,10,12-hexanitro- 2,4,6,8,10,12-hexaazaisowurtzitane (CL-20), respectively, have been investigated by DSC and TGA techniques. It has been found that there are two endothermic peaks at about 96°C and107 °C, due to polymorphic transition and melting of TMTA, where only small endothermic peaks were observed in the temperature region of 92.8-95.0oC for mixtures of RDX-TMTA, BCHMX-TMTA and CL-20-TMTA. These differences in endothermic temperatures of the pristine TMTA versus its mixtures could be a result of co-crystals formation. Moreover, only one complex step for decomposition of TMTA and RDX-TMTA was observed, while at least two steps were found for BCHMX-TMTA and CL-20-TMTA mixtures. TGA measurements showed that a mass loss of TMTA begins a t89.3 °C and has a peak temperature of 185.9 °C. In contrast, the mass loss of RDX-TMTA mixture begins at1 42.9 °C and has a peak t
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
JY - Firearms, ammunition, explosives, combat vehicles
OECD FORD branch
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Project
<a href="/en/project/TA03010647" target="_blank" >TA03010647: Plastic bonded energetic systems containing cis-1,3,4,6-tetranitrooktahydroimidazo-[4,5-d] imidazole (BCHMX)</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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