The first scorpionate ligand based on diazaphosphole

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900319" target="_blank" >RIV/00216275:25310/15:39900319 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/C5DT03589A" target="_blank" >http://dx.doi.org/10.1039/C5DT03589A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C5DT03589A" target="_blank" >10.1039/C5DT03589A</a>

Result language
angličtina
Original language name
The first scorpionate ligand based on diazaphosphole
Original language description
The reaction of PhBCl2 with 1H-1,2,4-?3-diazaphosphole in the presence of NEt3 gives a new scorpionate ligand, phenyl-tris(1,2,4-diazaphospholyl)borate (PhTdap). The coordination behaviour of this ligand toward transition and non-transition metals has been comprehensively studied. In the thallium(I) complex, Tl(PhTdap), ?2-N,N bonding supported with intramolecular ?3-phenyl coordination has been observed in the solid state. Tl(PhTdap) also shows unusual intermolecular ?-interactions between five-membered diazaphosphole rings and the thallium atom giving infinite molecular chains in the crystal. In the square planar complex [Pd(C,N-C6H4CH2NMe2)(PhTdap)], ?2-bonded scorpionate has been detected in both solution and in the solid state. For other studied compounds with the central metal ion Ti(IV), Mo(II), Mn(I), Fe(II), Ru(II), Co(II), Co(III), Ni(II) and Cd(II), the ?3-N,N,N coordination pattern was observed. Electronic properties of PhTdap and its ligand-field strength were elucidated f
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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