Effect of molar mass on film-forming properties of self-crosslinking latexes based on structured acrylic microgels
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901603" target="_blank" >RIV/00216275:25310/16:39901603 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.porgcoat.2015.12.003" target="_blank" >http://dx.doi.org/10.1016/j.porgcoat.2015.12.003</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.porgcoat.2015.12.003" target="_blank" >10.1016/j.porgcoat.2015.12.003</a>
Alternative languages
Result language
angličtina
Original language name
Effect of molar mass on film-forming properties of self-crosslinking latexes based on structured acrylic microgels
Original language description
The influence of molar mass of the shell layer of latex particles having core-shell morphology on film forming and final coating properties of self-crosslinking latexes based on keto-hydrazide crosslinking system was investigated. Structured latex particles were prepared by the semi-continuous non-seeded emulsion polymerization of acrylic monomers. The particle core was slightly crosslinked to prevent the copolymers forming the core phase from migration into the shell phase. The molar mass of copolymers forming the shell phase was gradually reduced by isooctyl 3-mercaptopropionate chain transfer agent included in the synthesis of the shell layers. The results confirmed theoretical predictions and revealed that even a slight amount of chain transfer agent added during the synthesis achieved a substantial lowering of minimum film-forming temperature and reduction of water sensitivity of latex coatings.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/TE02000011" target="_blank" >TE02000011: Research center of surface treatment</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Progress in Organic Coatings
ISSN
0300-9440
e-ISSN
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Volume of the periodical
92
Issue of the periodical within the volume
2016
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
23-28
UT code for WoS article
000370108300004
EID of the result in the Scopus database
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