Application of A4F-MALS for the Characterization of Polymers Prepared by Emulsion Polymerization: Comparison of the Molecular Structure of Styrene-Acrylate and Methyl Methacrylate-Acrylate Copolymers
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901605" target="_blank" >RIV/00216275:25310/16:39901605 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/03602559.2016.1146957" target="_blank" >http://dx.doi.org/10.1080/03602559.2016.1146957</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/03602559.2016.1146957" target="_blank" >10.1080/03602559.2016.1146957</a>
Alternative languages
Result language
angličtina
Original language name
Application of A4F-MALS for the Characterization of Polymers Prepared by Emulsion Polymerization: Comparison of the Molecular Structure of Styrene-Acrylate and Methyl Methacrylate-Acrylate Copolymers
Original language description
In this paper, organic asymmetric flow field flow fractionation coupled to a multi-angle light scattering detector is presented as a very efficient tool for the characterization of copolymers prepared by emulsion polymerization. The molar mass distribution and the extent of branching of styrene-acrylate copolymers have been compared with corresponding copolymers of methyl methacrylate. It has been found that the presence of acrylate monomer results in the increase of molar mass and formation of branched macromolecules due to intermolecular chain transfer to polymer similarly as in case of methyl methacrylate-acrylate copolymers. However, the effect is far less pronounced.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polymer-Plastics Technology and Engineering
ISSN
0360-2559
e-ISSN
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Volume of the periodical
55
Issue of the periodical within the volume
13
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
1365-1372
UT code for WoS article
000382953600005
EID of the result in the Scopus database
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