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Self-Crosslinking Latexes with Improved Flame Stability

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901629" target="_blank" >RIV/00216275:25310/16:39901629 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Self-Crosslinking Latexes with Improved Flame Stability

  • Original language description

    In this contribution the application of a novel flame retardant based on halogenophosphazene derivative in waterborne coatings based on self-crosslinking latexes was investigated. Hexaallylamino-cyclo-triphosphazene was synthesized by nucleophilic substitution of hexachloro-cyclo-triphosphazene with allyl amine. Latexes of functionalized core-shell particles bearing in the structure a covalently linked hexachloro-cyclo-triphosphazene were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. For interfacial crosslinking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, toughness and adhesive properties of resulting coatings. Moreover, the presence of the novel flame retardant increased the flame stability of coatings.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/TE02000011" target="_blank" >TE02000011: Research center of surface treatment</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings of the 4th International Conference on Chemical Technology

  • ISBN

    978-80-86238-94-4

  • ISSN

    2336-811X

  • e-ISSN

  • Number of pages

    6

  • Pages from-to

    325-330

  • Publisher name

    Česká společnost průmyslové chemie

  • Place of publication

    Praha

  • Event location

    Mikulov

  • Event date

    Apr 25, 2016

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article