Self-Crosslinking Latexes with Improved Flame Stability
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901629" target="_blank" >RIV/00216275:25310/16:39901629 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Self-Crosslinking Latexes with Improved Flame Stability
Original language description
In this contribution the application of a novel flame retardant based on halogenophosphazene derivative in waterborne coatings based on self-crosslinking latexes was investigated. Hexaallylamino-cyclo-triphosphazene was synthesized by nucleophilic substitution of hexachloro-cyclo-triphosphazene with allyl amine. Latexes of functionalized core-shell particles bearing in the structure a covalently linked hexachloro-cyclo-triphosphazene were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. For interfacial crosslinking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, toughness and adhesive properties of resulting coatings. Moreover, the presence of the novel flame retardant increased the flame stability of coatings.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/TE02000011" target="_blank" >TE02000011: Research center of surface treatment</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of the 4th International Conference on Chemical Technology
ISBN
978-80-86238-94-4
ISSN
2336-811X
e-ISSN
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Number of pages
6
Pages from-to
325-330
Publisher name
Česká společnost průmyslové chemie
Place of publication
Praha
Event location
Mikulov
Event date
Apr 25, 2016
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
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