Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901707" target="_blank" >RIV/00216275:25310/16:39901707 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s11998-015-9779-8" target="_blank" >http://dx.doi.org/10.1007/s11998-015-9779-8</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11998-015-9779-8" target="_blank" >10.1007/s11998-015-9779-8</a>

Result language
angličtina
Original language name
Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints
Original language description
Oxovanadium(IV) 2-ethylhexanoate was established as a new primary drier for alkyd-based paints. A series of experiments has demonstrated an excellent drying activity toward solvent-borne alkyd resins of different oil length at considerably lower metal concentration than optimal for commercial cobalt(II) 2-ethylhexanoate. The behavior in real paint was simulated on formulations bearing inhibitor of autooxidation. The detailed studies of the drying process have shown that the relatively slow initial step of autooxidation reaction, when compared with cobalt compounds, is compensated for by the absence of the induction times. Furthermore, the active oxovanadium(IV) species are not consumed during the drying processes as evidenced by EPR spectroscopic measurements.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
—

Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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