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Antimony Film Electrode Prepared with the Use of a Reversibly Deposited Mediator (Cd): Fabrication, Characterization and Application

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901866" target="_blank" >RIV/00216275:25310/16:39901866 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1149/2.0781614jes" target="_blank" >http://dx.doi.org/10.1149/2.0781614jes</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1149/2.0781614jes" target="_blank" >10.1149/2.0781614jes</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Antimony Film Electrode Prepared with the Use of a Reversibly Deposited Mediator (Cd): Fabrication, Characterization and Application

  • Original language description

    An antimony film electrode was prepared ex situ using a reversibly deposited mediator and applied to a model of metal ions (Hg(II)) by anodic stripping voltammetry. The electrochemical method for antimony film formation is based on a co-deposition of a metal of interest (Sb), with a reversibly deposited mediator (Cd), and then further on an oxidation of cadmium, with additional deposition of antimony by the appropriate potential. This serves to increase the density of concentrations of Sb atoms, promoting antimony film growth, and consequently helps to improve the electrochemical properties of the electrode. The structural and chemical information about antimony film electrodes prepared without and with a mediator were derived from data obtained via optical microscope, AFM and XPS analysis. Finally, the practical analytical application of the antimony film electrode (prepared with said mediator) was successfully tested by measuring the level of Hg(II) concentration in the certified reference material (1641d) and Vistula river water samples.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the Electrochemical Society

  • ISSN

    0013-4651

  • e-ISSN

  • Volume of the periodical

    163

  • Issue of the periodical within the volume

    14

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    "H1151"-"H1156"

  • UT code for WoS article

    000393852200128

  • EID of the result in the Scopus database