Stibinidene and Bismuthinidene as Two-Electron Donors for Transition Metals (Co and Mn)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39902109" target="_blank" >RIV/00216275:25310/16:39902109 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/chem.201601272" target="_blank" >http://dx.doi.org/10.1002/chem.201601272</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201601272" target="_blank" >10.1002/chem.201601272</a>

Result language
angličtina
Original language name
Stibinidene and Bismuthinidene as Two-Electron Donors for Transition Metals (Co and Mn)
Original language description
The reaction of stibinidene and bismuthinidene ArM [where Ar=C6H3-2,6-(CH=NtBu)(2); M=Sb (1), Bi (2)] with transition metal (TM) carbonyls Co-2(CO)(8) and Mn-2(CO)(10) produced unprecedented ionic complexes [(ArM)(2)Co(CO)(3)](+)[Co(CO)(4)](-) and [(ArM)(2)Mn(CO)(4)](+)[Mn(CO)(5)](-) [where M=Sb (3, 5), Bi (4, 6)]. The pnictinidenes 1 and 2 behaved as two-electron donors in this set of compounds. Besides the M -> TM bonds, the topological analysis also revealed a number of secondary interactions contributing to the stabilization of cationic parts of titled complexes.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA15-06609S" target="_blank" >GA15-06609S: Stibinidenes and Bismuthinidenes – A New Class of Ligands for Transition Metals</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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