Hydrosilylation in imino-substituded N- or C-monoanionic ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39902113" target="_blank" >RIV/00216275:25310/16:39902113 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ica.2016.07.042" target="_blank" >http://dx.doi.org/10.1016/j.ica.2016.07.042</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2016.07.042" target="_blank" >10.1016/j.ica.2016.07.042</a>

Result language
angličtina
Original language name
Hydrosilylation in imino-substituded N- or C-monoanionic ligands
Original language description
The reaction of HSiCl3 with 24[N-(2,6-diisopropylphenyl)iminomethyl]indolyl lithium (DipplMlndLi) provided disubstituted (DippAMInd)(DipplMlnd)SiCl (2), where one imino moiety of DipplMlnd ligand was reduced to amino group by Si-H fragment. In contract the reaction of HSiCl3 with 2-[N-(2,6-diisopropylphenyl)iminomethyl]phenyl lithium (DippIMPhLi) provided stable CH=N -> Si coordinated silane (DippIMPh)SiHCl2 (3). Heating of the toluene solution of 3 provided the hydrosilylated compound (DippAMPh)SiCl2 (4). It has been demonstrated that the rate of CH=N imino group reduction strongly depends on type of the anionic ligand.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA15-07091S" target="_blank" >GA15-07091S: Uncatalyzed Hydrosilylations Induced by N→Si Coordination</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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