VANADYL COMPLEX WITH TETRADENTATE MACROCYCLIC LIGAND AS A DRIER FOR SOLVENT-BORNE ALKYD PAINTS
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39910862" target="_blank" >RIV/00216275:25310/17:39910862 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
VANADYL COMPLEX WITH TETRADENTATE MACROCYCLIC LIGAND AS A DRIER FOR SOLVENT-BORNE ALKYD PAINTS
Original language description
This work is focused on study drying effects of vanadyl complex with Geodken’s macrocyclic ligand in solventborne alkyds of different oil length modified with soybean oil. Tested coatings, treated by the vanadium-based drier, were characterized by film drying time, relative hardness, EPR and IR spectroscopy. The results revealed its very good drying activity in short and medium-length alkyd resin compared to commercial cobalt(II) 2-ethylhexanoate. Study of kinetics revealed a negligible induction period of the autoxidation process in the test coatings threated by vanadyl complex. EPR spectroscopy showed the presence of vanadium(IV) species in alkyd films even after 100 days of curing.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
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OECD FORD branch
20506 - Coating and films
Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of the 5th International Conference on Chemical Technology
ISBN
978-80-86238-65-4
ISSN
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e-ISSN
neuvedeno
Number of pages
5
Pages from-to
457-561
Publisher name
Česká společnost průmyslové chemie
Place of publication
Praha
Event location
Mikulov
Event date
Apr 10, 2017
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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