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VANADYL COMPLEX WITH TETRADENTATE MACROCYCLIC LIGAND AS A DRIER FOR SOLVENT-BORNE ALKYD PAINTS

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39910862" target="_blank" >RIV/00216275:25310/17:39910862 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    VANADYL COMPLEX WITH TETRADENTATE MACROCYCLIC LIGAND AS A DRIER FOR SOLVENT-BORNE ALKYD PAINTS

  • Original language description

    This work is focused on study drying effects of vanadyl complex with Geodken’s macrocyclic ligand in solventborne alkyds of different oil length modified with soybean oil. Tested coatings, treated by the vanadium-based drier, were characterized by film drying time, relative hardness, EPR and IR spectroscopy. The results revealed its very good drying activity in short and medium-length alkyd resin compared to commercial cobalt(II) 2-ethylhexanoate. Study of kinetics revealed a negligible induction period of the autoxidation process in the test coatings threated by vanadyl complex. EPR spectroscopy showed the presence of vanadium(IV) species in alkyd films even after 100 days of curing.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings of the 5th International Conference on Chemical Technology

  • ISBN

    978-80-86238-65-4

  • ISSN

  • e-ISSN

    neuvedeno

  • Number of pages

    5

  • Pages from-to

    457-561

  • Publisher name

    Česká společnost průmyslové chemie

  • Place of publication

    Praha

  • Event location

    Mikulov

  • Event date

    Apr 10, 2017

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article