Dimeric and different polymeric copper(II) salicylates Crystal structure and spectral properties

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911355" target="_blank" >RIV/00216275:25310/17:39911355 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2017.02.081" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2017.02.081</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2017.02.081" target="_blank" >10.1016/j.molstruc.2017.02.081</a>

Result language
angličtina
Original language name
Dimeric and different polymeric copper(II) salicylates Crystal structure and spectral properties
Original language description
The small differences in synthesis condition led to formation of four new copper(II) salicylatocomplexes - two differently polymeric [Cu(4-MeOSal)(2)(mu-H2O)(2)](n)1, [Cu(mu-3,5-Br2Sal)(2)(H2O)(2)](n)2 and two dimeric [Cu(5-MeSal)(2)(MeOH)](2)center dot 2MeOH(3) [Cu(4-MeSal)(2)(EtOH)(2)](2) 4 compounds, where 4-MeOSal = 4-methoxysalicylate, 3,5-Br2Sal = 3, 5-dibromsalicylate, 5-MeSal = 5-methylsalicylate, and 4-MeSal = 4-methoxysalicylate monoanion. Complexes were characterized by elemental analysis, UV-Vis, infrared, EPR spectra and single crystal X-ray analysis. Spectral properties are in good agreement with structural information. Intermolecular interactions are responsible for building supramolecular structure. The complexes 1 and 2 build up 2D supramolecular structures by the O-H center dot center dot center dot O hydrogen bonds formation while the complexes 3 and 4 are forming 1D supramolecular chain of paddle wheel units and coordinated solvent molecules.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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