Monomeric C,N-Chelated Germanium Hydrides in N-C Bond Cleavage

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911693" target="_blank" >RIV/00216275:25310/17:39911693 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201700355" target="_blank" >http://dx.doi.org/10.1002/ejic.201700355</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201700355" target="_blank" >10.1002/ejic.201700355</a>

Result language
angličtina
Original language name
Monomeric C,N-Chelated Germanium Hydrides in N-C Bond Cleavage
Original language description
The synthesis of the monomeric organogermanium(II) hydrides [(LGeH) M(CO)(5)] [M = Cr (4), W (5)] by utilizing the C,N-chelating ligand L {L = [2-(CH2NEt2)-4,6-tBu(2)C(6)H(2)](-)} was explored. Stabilization of the GeH terminal bond in 4 and 5 was accompanied by a combination of electronic and steric protection of ligand L. The reactivity of the GeH terminal bond was also investigated, and attempts to reduce the polar C equivalent to N bond in tBuNC provided an unexpected N-C bond-cleavage reaction yielding organogermanium(II) cyanides [(LGeCN) M(CO)(5)] [M = Cr (6), W (7)] instead of a hydrogermylation reaction.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA15-07091S" target="_blank" >GA15-07091S: Uncatalyzed Hydrosilylations Induced by N→Si Coordination</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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