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Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912803" target="_blank" >RIV/00216275:25310/18:39912803 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21340/18:00328005

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.201800719" target="_blank" >https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.201800719</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/slct.201800719" target="_blank" >10.1002/slct.201800719</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts

  • Original language description

    A series of dicyanopyrazine and dicyanoimidazole derived push-pull molecules have been prepared and further investigated as photoredox catalysts. The fundamental properties of the catalysts were studied by DSC, X-ray analysis, absorption/emission spectra, and electrochemistry and were completed with the DFT results. The catalytic activity has been evaluated in visible light induced alpha-functionalization of amines (cross-dehydrogenative coupling and annulation reaction of tetrahydroisoquinolines). Thorough structure-property-catalytic activity relationships were elucidated. The developed series of tailored organic photoredox catalysts allows synthetic chemists to perform desired reactions under sustainable and mild conditions employing solely visible light as a source of energy.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ChemistrySelect

  • ISSN

    2365-6549

  • e-ISSN

  • Volume of the periodical

    3

  • Issue of the periodical within the volume

    16

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    9

  • Pages from-to

    4262-4270

  • UT code for WoS article

    000431626800017

  • EID of the result in the Scopus database

    2-s2.0-85046091861