Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912803" target="_blank" >RIV/00216275:25310/18:39912803 - isvavai.cz</a>
Alternative codes found
RIV/68407700:21340/18:00328005
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.201800719" target="_blank" >https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.201800719</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/slct.201800719" target="_blank" >10.1002/slct.201800719</a>
Alternative languages
Result language
angličtina
Original language name
Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts
Original language description
A series of dicyanopyrazine and dicyanoimidazole derived push-pull molecules have been prepared and further investigated as photoredox catalysts. The fundamental properties of the catalysts were studied by DSC, X-ray analysis, absorption/emission spectra, and electrochemistry and were completed with the DFT results. The catalytic activity has been evaluated in visible light induced alpha-functionalization of amines (cross-dehydrogenative coupling and annulation reaction of tetrahydroisoquinolines). Thorough structure-property-catalytic activity relationships were elucidated. The developed series of tailored organic photoredox catalysts allows synthetic chemists to perform desired reactions under sustainable and mild conditions employing solely visible light as a source of energy.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemistrySelect
ISSN
2365-6549
e-ISSN
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Volume of the periodical
3
Issue of the periodical within the volume
16
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
4262-4270
UT code for WoS article
000431626800017
EID of the result in the Scopus database
2-s2.0-85046091861