From Linear to T-Shaped Indan-1,3-dione Push-Pull Molecules: A Comparative Study
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912813" target="_blank" >RIV/00216275:25310/18:39912813 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/hlca.201800090" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/hlca.201800090</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/hlca.201800090" target="_blank" >10.1002/hlca.201800090</a>
Alternative languages
Result language
angličtina
Original language name
From Linear to T-Shaped Indan-1,3-dione Push-Pull Molecules: A Comparative Study
Original language description
A series of indan-1,3-dione-based linear, quadrupolar and T-shaped push-pull chromophores have been designed and synthesized by the Knoevenagel condensation and Pd-catalyzed Suzuki-Miyaura or Sonogashira cross-coupling reactions. The number and position of the peripheral donor branches attached to the central withdrawing indan-1,3-dione moiety have been varied jointly with the type of -linker used in order to modulate fundamental optoelectronic properties. The molecular structure of two chromophores has been confirmed by X-ray analysis. The thermal and optoelectronic properties have further been investigated by differential scanning calorimetry, electrochemistry, UV/Vis absorption spectroscopy, and DFT calculations. Based on these experimental and theoretical data, thorough structure-property relationships have been further evaluated and influence of the particular structural modification on chromophore properties has been discussed.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/EF16_025%2F0007445" target="_blank" >EF16_025/0007445: Organic redox couple based batteries for energetics of traditional and renewable resources.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Helvetica Chimica Acta
ISSN
0018-019X
e-ISSN
—
Volume of the periodical
101
Issue of the periodical within the volume
8
Country of publishing house
DE - GERMANY
Number of pages
13
Pages from-to
"e201800090-1"-"e201800090-13"
UT code for WoS article
000441747800002
EID of the result in the Scopus database
2-s2.0-85052374713