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From Linear to T-Shaped Indan-1,3-dione Push-Pull Molecules: A Comparative Study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912813" target="_blank" >RIV/00216275:25310/18:39912813 - isvavai.cz</a>

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/hlca.201800090" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/hlca.201800090</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/hlca.201800090" target="_blank" >10.1002/hlca.201800090</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    From Linear to T-Shaped Indan-1,3-dione Push-Pull Molecules: A Comparative Study

  • Original language description

    A series of indan-1,3-dione-based linear, quadrupolar and T-shaped push-pull chromophores have been designed and synthesized by the Knoevenagel condensation and Pd-catalyzed Suzuki-Miyaura or Sonogashira cross-coupling reactions. The number and position of the peripheral donor branches attached to the central withdrawing indan-1,3-dione moiety have been varied jointly with the type of -linker used in order to modulate fundamental optoelectronic properties. The molecular structure of two chromophores has been confirmed by X-ray analysis. The thermal and optoelectronic properties have further been investigated by differential scanning calorimetry, electrochemistry, UV/Vis absorption spectroscopy, and DFT calculations. Based on these experimental and theoretical data, thorough structure-property relationships have been further evaluated and influence of the particular structural modification on chromophore properties has been discussed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

    <a href="/en/project/EF16_025%2F0007445" target="_blank" >EF16_025/0007445: Organic redox couple based batteries for energetics of traditional and renewable resources.</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Helvetica Chimica Acta

  • ISSN

    0018-019X

  • e-ISSN

  • Volume of the periodical

    101

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    13

  • Pages from-to

    "e201800090-1"-"e201800090-13"

  • UT code for WoS article

    000441747800002

  • EID of the result in the Scopus database

    2-s2.0-85052374713