Molybdenum complexes of poly[(methylthio)methyl]borates
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912972" target="_blank" >RIV/00216275:25310/18:39912972 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2018.04.036" target="_blank" >http://dx.doi.org/10.1016/j.poly.2018.04.036</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2018.04.036" target="_blank" >10.1016/j.poly.2018.04.036</a>
Alternative languages
Result language
angličtina
Original language name
Molybdenum complexes of poly[(methylthio)methyl]borates
Original language description
Organometallic molybdenum compounds bearing poly[(methylthio)methyllborates, [(eta(3)-C3H5)Mo (CO)(2)(kappa(3)-PhTt)] and [Bu4N][{((eta(3)-C3H5)Mo(CO)(2)Cl)(2)(kappa(2):kappa(2)-RTt)], where PhTt = phenyltris[(methylthio) methyllborate and RTt = tetralds[(methylthio)methyl]borate, have been obtained by ligand exchange reaction from [(eta(3)-C3H5)Mo(CO)(2)(NCMe)(2)Cl] and appropriate borate. The PhTt ligand provides tridentate face-capping coordination to the central metal while the RTt acts as a bridging ligand and connects two [(eta(3)-C3H5)Mo(CO)(2)Cl] monomeric units by unusual kappa(2):kappa(2)-coordination mode. Both compounds were fully characterized by spectroscopic methods and X-ray crystallography.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
150
Issue of the periodical within the volume
August
Country of publishing house
GB - UNITED KINGDOM
Number of pages
5
Pages from-to
35-39
UT code for WoS article
000437053900006
EID of the result in the Scopus database
2-s2.0-85047154314