Triorganotin(IV) cation-promoted dimethyl carbonate synthesis from CO2 and methanol: solution and solid-state characterization of an unexpected diorganotin(IV)-oxo cluster
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912979" target="_blank" >RIV/00216275:25310/18:39912979 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c7nj05058e" target="_blank" >http://dx.doi.org/10.1039/c7nj05058e</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c7nj05058e" target="_blank" >10.1039/c7nj05058e</a>
Alternative languages
Result language
angličtina
Original language name
Triorganotin(IV) cation-promoted dimethyl carbonate synthesis from CO2 and methanol: solution and solid-state characterization of an unexpected diorganotin(IV)-oxo cluster
Original language description
Two novel C,N-chelated organotin(IV) complexes bearing weakly coordinating carborane moieties were prepared by the reaction of the corresponding C,N-chelated organotin(IV) chloride (i.e. LCNR2SnCl, R = n-Bu (1) and Ph (2); LCN = 2-(N,N-dimethylaminomethyl)phenyl)) with monocarba-closo-dodecaborate silver salt (AgCB11H12; Ag.3). Both products of the metathesis, [LCN(n-Bu)2Sn]+[CB11H12]- (4) and [LCNPh2Sn]+ [CB11H12]- (5), respectively, were characterized by both multinuclear NMR spectroscopy and elemental analysis. The instability of 4 and 5 towards water is discussed. The solid-state structure of LCN(n-Bu)2SnOH.B(C6F5)3 (4a) as a model compound with a Sn–O(H)...B linkage is also reported. The evaluation of the catalytic activity of 4 and 5 was carried out within the direct synthesis of dimethyl carbonate (DMC) from methanol and CO2. While 5 was shown to be definitively inactive, presumably due to cleavage of the Sn–Ph bond, compound 4 exhibits a beneficial action, since it leads to an amount of DMC higher than the stoichiometry (nDMC/nSn(cat) = 1.5). In addition, the solid state structures of [BnNMe3]+[CB11H12]- (6) and [(n-Bu)20Sn10O2(OMe)6(CO3)2]2+. 2[CB11H12]- (7), isolated as single-crystals and resulting from the recombination of 4 under the reaction conditions (methanol/CO2), were established by sc-XRD analyses within the term of this work as well. 6 and 7 were also fully characterized by IR spectroscopy, multinuclear NMR in solution and elemental analysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA16-01618S" target="_blank" >GA16-01618S: Ten-vertex dicarbaborane molecular assemblies via alkylation</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
New Journal of Chemistry
ISSN
1144-0546
e-ISSN
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Volume of the periodical
42
Issue of the periodical within the volume
10
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
8253-8260
UT code for WoS article
000434245500080
EID of the result in the Scopus database
2-s2.0-85047020582