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INHIBITION OF PREMATURE POLYMERIZATION OF CATIONICALLY CURABLE SYSTEMS BY TRIETHANOLAMINE

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39913035" target="_blank" >RIV/00216275:25310/18:39913035 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    INHIBITION OF PREMATURE POLYMERIZATION OF CATIONICALLY CURABLE SYSTEMS BY TRIETHANOLAMINE

  • Original language description

    This work concerns the inhibition of early polymerization of cationically polymerizable systems. Tested formulations contain 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate as a reactive monomer, triethanolamine as a stabilizer, and a photoinitiator. Three types of initiators were used: sulphonium salt (tris{4-[(4-acetylphenyl)sulfanyl]phenyl}sulfonium hexafluorophosphate), iodonium salt (iodonium (4-methyl-phenyl) [4-(2-ethylpropyl) phenyl] hexafluoro-phosphate)) and iron-arene salt (η5-2,4-cyclopentadien-1-yl) [(1,2,3,4,5,6-η)- (1-methylethyl)benzene]-iron hexafluorophosphate). Prepared formulations were periodically exposed at an increased temperature (60 °C). The long-term stability was tested by viscosity measurement. Viscosity change reflects changes in the distribution of molecular weights in the system or structural changes caused by premature polymerization. The flow behaviour was measured using rheometer Haake RotoVisco 1. The reactivity of the mixtures was tested by FTIR spectroscopy using Nicolet Avatar 320.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    9th International Symposium on Graphic Engineering and Design : proceedings

  • ISBN

  • ISSN

    2620-1429

  • e-ISSN

    neuvedeno

  • Number of pages

    4

  • Pages from-to

    213-216

  • Publisher name

    University of Novi Sad

  • Place of publication

    Novi Sad

  • Event location

    Novi Sad

  • Event date

    Nov 8, 2018

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article