Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39913487" target="_blank" >RIV/00216275:25310/18:39913487 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c8dt03357a" target="_blank" >http://dx.doi.org/10.1039/c8dt03357a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8dt03357a" target="_blank" >10.1039/c8dt03357a</a>

Result language
angličtina
Original language name
Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides
Original language description
The reactions of the boraquanidinato germylene (i-Pr)(2)NB(NDmp)(2)Ge (1) (Dmp = 2,6-Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while the treatment of 1 with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring, i.e. [N(R)C(O)N(Dmp)B(N(i-Pr)(2))N(Dmp)]Ge (R = t-Bu or Ad).
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA17-10377S" target="_blank" >GA17-10377S: Multideprotonable, ambiphilic and hybrid ligands with appropriate shape and electron pool for formation of oligometallic complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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