Reversible C=C Bond Activation by an Intramolecularly Coordinated Antimony(I) Compound

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915099" target="_blank" >RIV/00216275:25310/19:39915099 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201902968" target="_blank" >https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201902968</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201902968" target="_blank" >10.1002/chem.201902968</a>

Result language
angličtina
Original language name
Reversible C=C Bond Activation by an Intramolecularly Coordinated Antimony(I) Compound
Original language description
The reaction of N,C,N‐chelated stibinidene ArSb (1) (Ar=C6H3‐2,6‐(CH=NtBu)2) with selected N‐alkyl/aryl‐maleimides RN(C(O)CH)2 (R=Me, tBu, Ph) gave the addition products with bridged bicyclic [2.2.1] structure containing an antimony atom at the bridgehead position, fused with a 6‐membered benzene and a 5‐membered N‐alkyl/aryl‐pyrrolidine ring. These compounds were completely characterized. More importantly, additional studies showed that these reactions are reversible in solution, thereby representing an unprecedented reversible activation of a C=C bond by an antimony(I) compound.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA18-10222S" target="_blank" >GA18-10222S: From simple precursors to unprecedented heterocyclic systems containing heavier Group 15 elements</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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