From a 2,1-Benzazaarsole to Elusive 1-Arsanaphthalenes in One Step

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915102" target="_blank" >RIV/00216275:25310/19:39915102 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201900805" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201900805</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201900805" target="_blank" >10.1002/chem.201900805</a>

Result language
angličtina
Original language name
From a 2,1-Benzazaarsole to Elusive 1-Arsanaphthalenes in One Step
Original language description
The 2,1-benzazaarsole (1) showed a diene-like reactivity towards selected alkynes RC equivalent to CR (R=CO2Me, C5F4N) thus forming 1-arsa-1,4-dihydro-iminonaphthalenes 2 a and 3 a as hardly isolable intermediates, that underwent facile CH -> NH proton migration leading to before elusive substituted 1-arsanaphthalenes 2 b and 3 b that could be completely structurally characterized.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA18-10222S" target="_blank" >GA18-10222S: From simple precursors to unprecedented heterocyclic systems containing heavier Group 15 elements</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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