Thiaborane clusters with an exoskeletal B-H group

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915528" target="_blank" >RIV/00216275:25310/19:39915528 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/19:00503673 RIV/61388963:_____/19:00503673
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC00952C#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC00952C#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9cc00952c" target="_blank" >10.1039/c9cc00952c</a>

Result language
angličtina
Original language name
Thiaborane clusters with an exoskeletal B-H group
Original language description
The thiaboranes closo-1-SB11H11 (1a) and 12-I-closo-1-SB11H10 (1b) react with 4-(dimethylamino) pyridine under inert conditions upon the formation of the nido-type thiaboranes 9-B{(4-Me2N)C5NH4}(2)(H)-7-SB10H11 and 9-B{(4-Me2N)C5NH4}(2)(H)-5-I-7-SB10H10 containing an exoskeletal B-Hgroup. The same type of B-Hmoiety is also stabilised by one bipyridine molecule in a chelating fashion. These complexes are unstable in solution, and in air and hydrolyse to monodeboronated ionic compounds having [nido-7-SB10H11]- or [5-I-nido-7-SB10H10]- anions which are also products of the reactions of 1a and 1b with other N-bases such as pyridine, ammonia and DABCO. The extrusion of one boron and one sulphur atom takes place when 1a reacts with 2,6-di-tert-butylpyridine to yield decaborane.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA17-08045S" target="_blank" >GA17-08045S: Getting stronger together: exo-substituted heteroboranes and their adducts as suitable motifs for exploration of non-covalent interactions</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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