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High Electronically Conductive Tungsten Phosphate Glass-Ceramics

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916624" target="_blank" >RIV/00216275:25310/20:39916624 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.mdpi.com/2079-4991/10/12/2515" target="_blank" >https://www.mdpi.com/2079-4991/10/12/2515</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/nano10122515" target="_blank" >10.3390/nano10122515</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    High Electronically Conductive Tungsten Phosphate Glass-Ceramics

  • Original language description

    High electronically conductive tungsten phosphate glass-ceramics have been prepared by the controlled crystallization of binary 60WO3–40P2O5 glass in the temperature range from 700 to 935 C and for 1 to 24 h. The substantial increase in the conductivity for four orders of magnitudeis a result of the formation of electronically conductive W2O3(PO4)2 and WO3 phases. At low crystallization temperature the dominantW2O3(PO4)2 phase is created, whereas at 935 C for 24 h theformation of semiconducting WO3 crystallites of an average size of 80 nm enhances the conductivity to the highest value of 1.64 E10-4 (Ohm.cm)–1 at 30 C. The course of the crystallization and its impact on this exceptionally high electronic transport of binary tungsten phosphate glass-ceramics has been discussed in detail. Since such highly electronically conductive WO3-based glass-ceramics have a great potential as cathode/anode materials in solid state batteries and as electrocatalysts in fuel cells, it is of interest to provide a novel insight into the improvement of their electrical properties.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

    <a href="/en/project/GA18-01976S" target="_blank" >GA18-01976S: New prospective phosphate and borophosphate glasses and glass-ceramics</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Nanomaterials

  • ISSN

    2079-4991

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    13

  • Pages from-to

    "2515-1"-"1-2515-13"

  • UT code for WoS article

    000603098100001

  • EID of the result in the Scopus database