Homocoupling of CO and isocyanide mediated by a C,C '-bis(silylenyl)-substituted ortho-carborane
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916648" target="_blank" >RIV/00216275:25310/20:39916648 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc08680c#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc08680c#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9cc08680c" target="_blank" >10.1039/c9cc08680c</a>
Alternative languages
Result language
angličtina
Original language name
Homocoupling of CO and isocyanide mediated by a C,C '-bis(silylenyl)-substituted ortho-carborane
Original language description
The unexpected reactivity of the o-carborane supported bis-silylene [(LSi:)C](2)B(10)H(10)1 {L= PhC(tBuN)(2)} towards carbon monoxide and 2,6-dimethylphenyl isocyanide is reported. While the reaction of 1 with CO leads selectively to the novel head-to-head coupling and C-O cleavage product 2 from two molecules 1 and four molecules CO, the reaction of 1 with 2,6-dimethylphenyl isocyanide affords solely the 1 : 2 molar head-to-tail coupling product 3 with a SiC bond.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
—
Volume of the periodical
56
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
747-750
UT code for WoS article
000507866200011
EID of the result in the Scopus database
2-s2.0-85077951522