Organogermanium(II) Hydrides as a Source of Highly Soluble LiH
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916708" target="_blank" >RIV/00216275:25310/20:39916708 - isvavai.cz</a>
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202000970" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202000970</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202000970" target="_blank" >10.1002/chem.202000970</a>
Alternative languages
Result language
angličtina
Original language name
Organogermanium(II) Hydrides as a Source of Highly Soluble LiH
Original language description
The reactions of monomeric C,N-chelated organogermanium(II) hydride L(H)Ge.BH3 with organolithium salts RLi yielded lithium hydrogermanatoborates (Li(THF)(2){BH3[L(H)GeR]})(2). Compound (Li(THF)(2){BH3[L(H)GePh]})(2) was used as a source of LiH for the reduction of organic C=O or C=N bonds in nonpolar solvents accompanied by the elimination of a neutral complex L(Ph)Ge.BH3. The interaction of (Li(THF)(2){BH3[L(H)GePh]})(2) with the polar C=O bond was further investigated by computational studies revealing a plausible geometry of a pre-reactive intermediate. The experimental and theoretical studies suggest that, although the Li atom of (Li(THF)(2){BH3[L(H)GePh]})(2) coordinates the C=O bond, the GeH fragment is the active species in the reduction reaction. Finally, benzaldehyde was reduced by a mixture of L(H)Ge.BH3 with PhLi in nonpolar solvents.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA20-10417S" target="_blank" >GA20-10417S: Auto-ionizated Main Group Cations as Catalysts for Ring-Opening Polymerization reactions</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
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Volume of the periodical
26
Issue of the periodical within the volume
27
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
6070-6075
UT code for WoS article
000528860600001
EID of the result in the Scopus database
2-s2.0-85084217809