Probing the limits of oxidative addition of C(sp3)-X bonds toward selected N,C,N-chelated bismuth(I) compounds
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916710" target="_blank" >RIV/00216275:25310/20:39916710 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.organomet.0c00418" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.organomet.0c00418</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.organomet.0c00418" target="_blank" >10.1021/acs.organomet.0c00418</a>
Alternative languages
Result language
angličtina
Original language name
Probing the limits of oxidative addition of C(sp3)-X bonds toward selected N,C,N-chelated bismuth(I) compounds
Original language description
The reactivity of two N,C,N-chelated bismuthinidenes, that is, [2,6-(tBuN═CH)2C6H3]Bi (1) and its metastable analogue [2,6-(Me2NCH2)2C6H3]Bi (2), toward organic substrates containing C(sp3)–X bond (where X = I or OTf) is reported. The aim of this study is to prove the potential of the Bi(I) center in 1 and 2 to participate in an oxidative addition toward C–X bonds under formation of corresponding trivalent bismuth compounds. The influence of the substrate is examined; thus, simple primary alkyls (including fluorinated ones) as well as more branched substrates are considered to find the limits of these reactions and recognize the differences in the reactivity between 1 and 2. All products were characterized by means of high-resolution electrospray ionization mass spectrometry (ESI-MS); 1H, 13C, and 19F NMR spectroscopy; and single-crystal X-ray diffraction analysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA18-10222S" target="_blank" >GA18-10222S: From simple precursors to unprecedented heterocyclic systems containing heavier Group 15 elements</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
39
Issue of the periodical within the volume
23
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
"4320–4328"
UT code for WoS article
000599997800030
EID of the result in the Scopus database
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