All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Probing the limits of oxidative addition of C(sp3)-X bonds toward selected N,C,N-chelated bismuth(I) compounds

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916710" target="_blank" >RIV/00216275:25310/20:39916710 - isvavai.cz</a>

  • Result on the web

    <a href="https://pubs.acs.org/doi/10.1021/acs.organomet.0c00418" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.organomet.0c00418</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acs.organomet.0c00418" target="_blank" >10.1021/acs.organomet.0c00418</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Probing the limits of oxidative addition of C(sp3)-X bonds toward selected N,C,N-chelated bismuth(I) compounds

  • Original language description

    The reactivity of two N,C,N-chelated bismuthinidenes, that is, [2,6-(tBuN═CH)2C6H3]Bi (1) and its metastable analogue [2,6-(Me2NCH2)2C6H3]Bi (2), toward organic substrates containing C(sp3)–X bond (where X = I or OTf) is reported. The aim of this study is to prove the potential of the Bi(I) center in 1 and 2 to participate in an oxidative addition toward C–X bonds under formation of corresponding trivalent bismuth compounds. The influence of the substrate is examined; thus, simple primary alkyls (including fluorinated ones) as well as more branched substrates are considered to find the limits of these reactions and recognize the differences in the reactivity between 1 and 2. All products were characterized by means of high-resolution electrospray ionization mass spectrometry (ESI-MS); 1H, 13C, and 19F NMR spectroscopy; and single-crystal X-ray diffraction analysis.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA18-10222S" target="_blank" >GA18-10222S: From simple precursors to unprecedented heterocyclic systems containing heavier Group 15 elements</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Organometallics

  • ISSN

    0276-7333

  • e-ISSN

  • Volume of the periodical

    39

  • Issue of the periodical within the volume

    23

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    "4320–4328"

  • UT code for WoS article

    000599997800030

  • EID of the result in the Scopus database