All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Ferrocene donor linked to pyridine/pyridinium acceptor via a systematically enlarged pi-linker

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39917906" target="_blank" >RIV/00216275:25310/21:39917906 - isvavai.cz</a>

  • Result on the web

    <a href="http://DOI" target="_blank" >http://DOI</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d1ra08186a" target="_blank" >10.1039/d1ra08186a</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Ferrocene donor linked to pyridine/pyridinium acceptor via a systematically enlarged pi-linker

  • Original language description

    Nine chromophores with ferrocene donor and pyridine/pyridinium acceptors have been prepared and further investigated. The performed X-ray analysis showed partially polarized and geometrically oblate pyridine unit. An extension of the pi-system and N-quaternization were revealed as suitable tools for exclusive manipulation of the LUMO with the almost steady HOMO. Whereas the electrochemical HOMO-LUMO gap can be tuned from 3.01 to 1.49 eV, the high- and low-energy absorption bands were found within the range of 280-402/456-547 nm. The pyridinium chromophores showed distinct negative solvatochromism. A thorough DFT analysis has been performed; it turned out that ferrocene donor is capable of two principal D-A interactions, whose employment depends on the appended electron-withdrawing moiety.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

    <a href="/en/project/EF16_025%2F0007445" target="_blank" >EF16_025/0007445: Organic redox couple based batteries for energetics of traditional and renewable resources.</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    RSC ADVANCES

  • ISSN

    2046-2069

  • e-ISSN

  • Volume of the periodical

    11

  • Issue of the periodical within the volume

    61

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    10

  • Pages from-to

    38804-38813

  • UT code for WoS article

    000725660400001

  • EID of the result in the Scopus database

    2-s2.0-85121203641