On the edge of the steric repulsion and reactivity of bulky anilines; a case study of chloro(imino)phosphine synthesis
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39918350" target="_blank" >RIV/00216275:25310/21:39918350 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlepdf/2021/dt/d1dt02445k" target="_blank" >https://pubs.rsc.org/en/content/articlepdf/2021/dt/d1dt02445k</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1dt02445k" target="_blank" >10.1039/d1dt02445k</a>
Alternative languages
Result language
angličtina
Original language name
On the edge of the steric repulsion and reactivity of bulky anilines; a case study of chloro(imino)phosphine synthesis
Original language description
2-Benzhydryl-4-methyl-6-(1,1 '-diphenyl-2-phenyl-ethyl)aniline was prepared by a three-step process. 2,6-Bis(benzhydryl)-4-methyl-aniline was protected by Schiff coupling, then benzylated and finally dealkylated by using hydrochloric acid and methanol. The resulting compound exhibits one of the highest buried volumes around the nitrogen atom of anilines prepared so far, but it reacts with phosphorus trichloride and triethylamine to give a monomeric chloro(imino)phosphine.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
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Volume of the periodical
50
Issue of the periodical within the volume
40
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
14352-14361
UT code for WoS article
000699953400001
EID of the result in the Scopus database
2-s2.0-85117453855