Utilization of CO2-Available Organocatalysts for Reactions with Industrially Important Epoxides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F22%3A39919216" target="_blank" >RIV/00216275:25310/22:39919216 - isvavai.cz</a>
Result on the web
<a href="https://www.mdpi.com/2073-4344/12/3/298" target="_blank" >https://www.mdpi.com/2073-4344/12/3/298</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/catal12030298" target="_blank" >10.3390/catal12030298</a>
Alternative languages
Result language
angličtina
Original language name
Utilization of CO2-Available Organocatalysts for Reactions with Industrially Important Epoxides
Original language description
Recent knowledge in chemistry has enabled the material utilization of greenhouse gas (CO2) for the production of organic carbonates using mild reaction conditions. Organic carbonates, especially cyclic carbonates, are applicable as green solvents, electrolytes in batteries, feedstock for fine chemicals and monomers for polycarbonate production. This review summarizes new developments in the ring opening of epoxides with subsequent CO2-based formation of cyclic carbonates. The review highlights recent and major developments for sustainable CO2 conversion from 2000 to the end of 2021 abstracted by Web of Science. The syntheses of epoxides, especially from bio-based raw materials, will be summarized, such as the types of raw material (vegetable oils or their esters) and the reaction conditions. The aim of this review is also to summarize and to compare the types of homogeneous non-metallic catalysts. The three reaction mechanisms for cyclic carbonate formation are presented, namely activation of the epoxide ring, CO2 activation and dual activation.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10511 - Environmental sciences (social aspects to be 5.7)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Catalysts
ISSN
2073-4344
e-ISSN
2073-4344
Volume of the periodical
12
Issue of the periodical within the volume
3
Country of publishing house
CH - SWITZERLAND
Number of pages
41
Pages from-to
298
UT code for WoS article
000776896900001
EID of the result in the Scopus database
2-s2.0-85126032254