Reactivity of a N-Coordinated Germylene-Borane Complex: From Ge -> B to Ge -> Ga Coordination
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F22%3A39919461" target="_blank" >RIV/00216275:25310/22:39919461 - isvavai.cz</a>
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202202639" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202202639</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202202639" target="_blank" >10.1002/chem.202202639</a>
Alternative languages
Result language
angličtina
Original language name
Reactivity of a N-Coordinated Germylene-Borane Complex: From Ge -> B to Ge -> Ga Coordination
Original language description
Reactivity studies of the Ge-II -> B complex L-(CI)Ge center dot BH3 (1; L=2-Et2NCH2-4,6-tBu(2)-C6H2) were performed to determine the effect on the Ge-II -> B donation. N-coordinated compounds L(OtBu)Ge.BH3 (2) and [LGe.BH3](2) (3) were prepared. The possible tuning of the Ge-II -> B interaction was proved experimentally, yielding compounds 1-PPh2-8-(LGe)C10H6 (4) and L(CI)Ge.GaCl3 (5) without a Ge-II -> B interaction. In 5, an unprecedented Ge-II -> Ga coordination was revealed. The experimental results were complemented by a theoretical study focusing on the bonding in 1-5. The different strength of the Ge-II -> E (E=B, Ga) donation was evaluated by using energy decomposition analysis. The basicity of different L(X)Ge groups through proton affinity is also assessed.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA20-10417S" target="_blank" >GA20-10417S: Auto-ionizated Main Group Cations as Catalysts for Ring-Opening Polymerization reactions</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
1521-3765
Volume of the periodical
28
Issue of the periodical within the volume
70
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
"e202202639"
UT code for WoS article
000871809000001
EID of the result in the Scopus database
2-s2.0-85141148997